Rayleigh-Taylor Instability in Soft Viscoelastic Solids.

We present an experimental characterization of the gravity-driven Rayleigh-Taylor instability in viscoelastic solids. The instability creates periodic patterns on the free surface of the soft solids that are distinct from the previously studied elastic Rayleigh-Taylor instability. The experimental results are supported by the linear stability analysis reported here. We identify the dependence of the steady-state pattern of deformations on the gel's geometry, complex shear modulus, and surface tension. This study provides quantitative measures applicable to the design of tunable surface textures, soft machines, and 3D structures.

A quantitative study of the effect of flow on the photopolymerization of fibers.

Pulsed-UV light in the continuous flow of a photo-crosslinkable liquid can result in gelation and is a useful method to produce soft microfibers with uniform sizes. With modeling and experiments, we characterize some aspects of this fiber fabrication process. We model the spatial concentration profiles of radical species and molecular oxygen in the flow direction during light exposure, and predict the critical conditions for the onset of fiber formation and compare these predictions with experimental observations. We also characterize the different regimes of microfiber production (no polymerization, non-uniform fibers, and uniform microfibers), qualitatively characterize the rigidity of the fibers, and demonstrate that we can predictably control the length of the produced microfibers for a range of process parameters.